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When a weak acid is titrated with a weak base, the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is determined by the sizes of K a and K b.
E) is no longer affected by addition of base.

F) D) and E)
G) A) and C)

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Which one of the following is the best representation of the titration curve that will be obtained in the titration of a weak diprotic acid H2A (0.10 mol L1) with a strong base of the same concentration? Which one of the following is the best representation of the titration curve that will be obtained in the titration of a weak diprotic acid H<sub>2</sub>A (0.10 mol L<sup>−</sup><sup>1</sup>)  with a strong base of the same concentration?   A) A B) B C) C D) D E) E


A) A
B) B
C) C
D) D
E) E

F) B) and C)
G) C) and D)

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You need to prepare a buffer solution with a pH of 4.00, using NaF and HF. What ratio of the ratio of [base]/[acid] should be used in making the buffer? For HF, Ka = 7.2 × 104.


A) [base]/[acid] = 0.14
B) [base]/[acid] = 0.42
C) [base]/[acid] = 2.36
D) [base]/[acid] = 7.20
E) None of these choices are correct.

F) A) and B)
G) A) and E)

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A sample of a monoprotic acid (HA) weighing 0.384 g is dissolved in water and the solution is titrated with aqueous NaOH. If 30.0 mL of 0.100 M NaOH is required to reach the equivalence point, what is the molar mass of HA?


A) 37.0 g/mol
B) 81.0 g/mol
C) 128 g/mol
D) 20.3 g/mol
E) 211 g/mol

F) B) and E)
G) A) and B)

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A popular buffer solution consists of carbonate (CO32) and hydrogen carbonate (HCO3) conjugate acid-base pair. Which, if any, of the following such buffers can neutralize the greatest amount of added hydrochloric acid, while remaining within its buffer range?


A) 1 L of 0.9 M CO 3 2 and 0.1 M HCO 3
B) 1 L of 0.1 M CO 3 2 and 0.9 M HCO 3
C) 1 L of 0.5 M CO 3 2 and 0.5 M HCO 3
D) 1 L of 0.1 M CO32 and 0.1 M HCO3
E) They can all neutralize the same amount of hydrochloric acid.

F) None of the above
G) B) and E)

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A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH. What is the pH of the solution after 28.0 mL of NaOH have been added to the acid?


A) 0.85
B) 0.75
C) 0.66
D) 0.49
E) 3.8

F) A) and B)
G) B) and E)

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What is the maximum amount of sodium sulfate that can be added to 1.00 L of 0.0020 M Ca(NO3) 2 before precipitation of calcium sulfate begins? Ksp = 2.4 × 105 for calcium sulfate.


A) 1.2 × 10 2 mol
B) 4.9 × 10 3 mol
C) 3.5 × 10 3 mol
D) 1.2 × 10 5 mol
E) 4.8 × 10 8 mol

F) C) and D)
G) B) and C)

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The salts X(NO3) 2 and Y(NO3) 2 (where X+ and Y+ are metal ions) are dissolved in water to give a solution which is 0.1 M in each of them. Using the Ksp values listed below, decide which aqueous reagent, if any, will definitely precipitate X+ before precipitating Y+ from solution. Given Ksp values:XCl2, 1 × 105 YCl2, 1 × 1010 X(OH) 2, 1 × 1010 Y(OH) 2, 1 × 105


A) 1 M NH 3
B) 1 M HCl
C) 1 M HNO 3
D) 1 M NaCl
E) None of these choices are correct.

F) A) and B)
G) C) and D)

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The salts X(NO3) 2 and Y(NO3) 2 (where X+ and Y+ are metal ions) are dissolved in water to give a solution which is 0.1 M in each of them. Using the Ksp values listed below, decide which aqueous reagent, if any, will definitely precipitate X+ before precipitating Y+ from solution. Given Ksp values:XCl2, 1 × 105 YCl2, 1 × 1010 X(OH) 2, 1 × 1010 Y(OH) 2, 1 × 105


A) 1 M NaCl
B) 1 M HCl
C) 1 M HNO 3
D) 1 M NaOH
E) None of these choices are correct.

F) B) and C)
G) A) and E)

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What is the [H3O+] in a solution that consists of 1.2 M HClO and 2.3 M NaClO? Ka = 3.5 × 108


A) 7.8 × 10 9 M
B) 1.8 × 10 8 M
C) 6.7 × 10 8 M
D) 1.6 × 10 7 M
E) None of these choices are correct.

F) B) and D)
G) B) and E)

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The salts X(NO3) 2 and Y(NO3) 2 (where X+ and Y+ are metal ions) are dissolved in water to give a solution which is 0.1 M in each of them. Using the Ksp values listed below, decide which aqueous reagent, if any, will definitely precipitate X+ before precipitating Y+ from solution. Given Ksp values:XCl2, 1 × 105 YCl2, 1 × 1010 X(OH) 2, 1 × 1010 Y(OH) 2, 1 × 105


A) 1 M NaNO 3
B) 1 M HCl
C) 1 M HNO 3
D) 1 M NaCl
E) None of these choices are correct.

F) A) and E)
G) B) and D)

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The solubility of lead(II) chloride is 0.45 g/100 mL of solution. What is the Ksp of PbCl2?


A) 4.9 × 10 2
B) 1.7 × 10 5
C) 8.5 × 10 6
D) 4.2 × 10 6
E) < 1.0 × 10 6

F) C) and D)
G) B) and E)

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Write the ion product expression for magnesium fluoride, MgF2.


A) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
B) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
C) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
D) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
E) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)

F) A) and B)
G) B) and C)

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What is the [H3O+] in a buffer that consists of 0.30 M HCOOH and 0.20 M HCOONa? For HCOOH, Ka = 1.7 × 104


A) 1.1 × 10 4 M
B) 2.6 × 10 4 M
C) 4.3 × 10 4 M
D) 6.7 × 10 5 M
E) None of these choices are correct.

F) A) and C)
G) C) and D)

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