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The neutral monodentate ligand L forms the complex ion [CrL6]2+, and the magnetic properties of this complex correspond to 2 unpaired electrons. Is L a strong-field or weak-field ligand? Explain your reasoning.

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L is a strong-field ligand. Reasoning (a...

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The ion [Co(NH3) 6]2+ is octahedral and high spin. This complex is


A) paramagnetic, with 1 unpaired electron.
B) paramagnetic, with 3 unpaired electrons.
C) paramagnetic, with 4 unpaired electrons.
D) paramagnetic, with 5 unpaired electrons.
E) diamagnetic.

F) B) and D)
G) A) and B)

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The best name for K4[FeCl2(CN) 4] is


A) tetrapotassium dichlorodicyanoiron(II) .
B) potassium dichlorodicyanoiron(II) .
C) potassium dichlorodicyanoferrate(III) .
D) tetrapotassium dichlorobis(cyano) iron(III) .
E) potassium dichlorotetracyanoferrate(II) .

F) A) and C)
G) B) and E)

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How many 3d electrons does a V3+ ion have?


A) 6
B) 5
C) 4
D) 3
E) 2

F) A) and E)
G) C) and E)

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Predict the number of unpaired electrons in the [Fe(CN)6]3- ion.

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The numbers of geometrical isomers and optical isomers of the complex ion [Co(en) 3]3+ are, respectively,


A) 2 and 2.
B) 1 and 1.
C) 3 and 2.
D) 1 and 2.
E) 2 and 4.

F) B) and E)
G) A) and E)

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Write the chemical formula of diamminedichloroplatinum(II).

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How many 3d electrons does a Mn2+ ion have?


A) 1
B) 2
C) 3
D) 4
E) 5

F) B) and D)
G) A) and D)

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The electron configuration of a nickel atom is


A) [Ar]4s23d6.
B) [Ar]4s13d7.
C) [Ar]3d8.
D) [Ar]4s23d8.
E) [Ar]3d10.

F) A) and E)
G) D) and E)

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In the coordination compound K2[Co(en) Cl4], the coordination number (C.N.) and oxidation number (O.N.) of cobalt are


A) C.N. = 6; O.N. = +2.
B) C.N. = 6; O.N. = +3.
C) C.N. = 5; O.N. = +2.
D) C.N. = 5; O.N. = +4.
E) C.N. = 4; O.N. = +3.

F) C) and E)
G) B) and D)

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Give the coordination number (C.N.) and oxidation number (O.N.) of the metal atom in the coordination compound [Cr(NH3) 2(en) Cl2].


A) C.N. = 4; O.N. = +2.
B) C.N. = 5; O.N. = +3.
C) C.N. = 5; O.N. = +2.
D) C.N. = 6; O.N. = +3.
E) C.N. = 6; O.N. = +2.

F) B) and E)
G) A) and D)

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In the complex ion [ML6]n+, Mn+ has seven d electrons and L is a strong field ligand. According to crystal field theory, the magnetic properties of the complex ion correspond to how many unpaired electrons?


A) 0
B) 1
C) 2
D) 3
E) 5

F) B) and D)
G) B) and E)

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Name the complex ion [Ni(CN)4]2-.

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tetracyano...

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In the complex ion [ML6]n+, Mn+ has six d electrons and L is a weak field ligand. According to crystal field theory, the magnetic properties of the complex ion correspond to how many unpaired electrons?


A) 0
B) 1
C) 2
D) 3
E) 4

F) B) and D)
G) B) and C)

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The electron configuration of a Co3+ ion is


A) [Ar]3d6.
B) [Ar]4s13d5.
C) [Ar] 4s23d4.
D) [Ar]3d5.
E) [Ar]3d4.

F) A) and E)
G) D) and E)

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The coordination compound shown below has The coordination compound shown below has   A) two monodentate ligands and two bidentate ligands. B) three monodentate ligands and two bidentate ligands. C) four monodentate ligands and two bidentate ligands. D) one monodentate ligand and four bidentate ligands. E) four bidentate ligands.


A) two monodentate ligands and two bidentate ligands.
B) three monodentate ligands and two bidentate ligands.
C) four monodentate ligands and two bidentate ligands.
D) one monodentate ligand and four bidentate ligands.
E) four bidentate ligands.

F) A) and C)
G) A) and B)

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What terms describe the geometric isomers that are possible for the complex [CrF2Cl4]3-?

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Which of these ligands produces the weakest crystal field?


A) CN-
B) I-
C) OH-
D) H2O
E) NH3

F) B) and D)
G) B) and C)

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The electron configuration of a Cr3+ ion is


A) [Ar]3d5.
B) [Ar]4s13d2.
C) [Ar]3d3.
D) [Ar]4s13d5.
E) [Ar]4s23d4.

F) C) and D)
G) B) and E)

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What is the coordination number of silver in [Ag(NH3)2]Cl?

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