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Which of the following covalent bonds is the most polar (i.e., highest percent ionic character) ?


A) Al - I
B) Si - I
C) Al - Cl
D) Si - Cl
E) Si - P

F) A) and E)
G) A) and B)

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Use the Born-Haber cycle to calculate the lattice energy of KCl(s) given the following data: Δ\Delta H(sublimation) K = 79.2 kJ/mol I1 (K) = 418.7 kJ/mol Bond energy (Cl-Cl) = 242.8 kJ/mol EA (Cl) = 348 kJ/mol Δ\Delta H  Use the Born-Haber cycle to calculate the lattice energy of KCl(s) given the following data:  \Delta H(sublimation) K = 79.2 kJ/mol I<sub>1</sub> (K) = 418.7 kJ/mol Bond energy (Cl-Cl) = 242.8 kJ/mol EA (Cl) = 348 kJ/mol  \Delta H   (KCl(s) ) = -435.7 kJ/mol A) -165 kJ/mol B) 288 kJ/mol C) 629 kJ/mol D) 707 kJ/mol E) 828 kJ/mol (KCl(s) ) = -435.7 kJ/mol


A) -165 kJ/mol
B) 288 kJ/mol
C) 629 kJ/mol
D) 707 kJ/mol
E) 828 kJ/mol

F) A) and C)
G) C) and D)

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Which one of the following compounds does not follow the octet rule?


A) NF3
B) CO2
C) CF4
D) Br2
E) NO

F) A) and E)
G) C) and E)

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The Si - Cl bond has less ionic character than the C - Cl bond.

A) True
B) False

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Write a Lewis structure for SO3 that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for SO3 that obey the octet rule.

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blured image Total number of res...

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How many covalent bonds will be drawn to bromine in BrO3- for the dot structure that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s) .


A) 3
B) 4
C) 5
D) 6
E) 7

F) A) and E)
G) C) and D)

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What is the formal charge on the singly bonded oxygens in the Lewis structure for the carbonate ion?


A) -2
B) -1
C) 0
D) +1
E) +2

F) A) and B)
G) A) and C)

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Complete this statement: Coulomb's law states that the magnitude of the force of interaction between two charged bodies is


A) directly proportional to the product of the charges on the bodies and directly proportional to the distance separating them.
B) directly proportional to the product of the charges on the bodies, and inversely proportional to the square of the distance separating them.
C) inversely proportional to the product of the charges on the bodies, and directly proportional to the square of the distance separating them.
D) directly proportional to the sum of the charges on the bodies, and inversely proportional to the square of the distance separating them.

E) C) and D)
F) A) and C)

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What is the formal charge on phosphorus in a Lewis structure for the phosphate ion that satisfies the octet rule?


A) -2
B) -1
C) 0
D) +1
E) +2

F) D) and E)
G) C) and E)

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Which of the following solids would have the highest melting point?


A) NaF
B) NaCl
C) NaBr
D) NaI

E) All of the above
F) A) and C)

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The Lewis structure for CS2 is:


A) The Lewis structure for CS<sub>2</sub> is: A)    B)    C)    D)
B) The Lewis structure for CS<sub>2</sub> is: A)    B)    C)    D)
C) The Lewis structure for CS<sub>2</sub> is: A)    B)    C)    D)
D) The Lewis structure for CS<sub>2</sub> is: A)    B)    C)    D)

E) B) and D)
F) A) and B)

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Which of the elements listed below is the least electronegative?


A) Sr
B) V
C) Ni
D) P
E) I

F) C) and E)
G) All of the above

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Estimate the enthalpy change for the combustion of one mole of acetylene, C2H2, to form carbon dioxide and water vapor. BE(C-H) = 456 kJ/mol BE(C \equiv C) = 962 kJ/mol BE(O=O) = 499 kJ/mol BE(C=O) = 802 kJ/mol BE(O-H) = 462 kJ/mol


A) -1759 kJ/mol
B) +653 kJ/mol
C) +1010 kJ/mol
D) -1010 kJ/mol
E) -155 kJ/mol

F) B) and E)
G) D) and E)

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What is the formal charge on sulfur in the best Lewis structure for the SCN- (thiocyanate) ion?


A) +2
B) -2
C) +1
D) -1
E) 0

F) B) and E)
G) A) and B)

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Which of the following solids would have the lowest melting point?


A) KI
B) KBr
C) KCl
D) KF

E) A) and B)
F) A) and C)

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A nonpolar covalent bond (i.e., pure covalent) would form in which one of the following pairs of atoms?


A) Na - Cl
B) H - Cl
C) Li - Br
D) Se - Br
E) Br - Br

F) A) and B)
G) A) and C)

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Use the bond enthalpy data given to estimate the heat released when 25.0 g of acetylene gas, C2H2, burns in excess oxygen to yield carbon dioxide and water vapor at 25°C. BE(C-C) = 347 kJ/mol BE(C \equiv C) = 812 kJ/mol BE(C=O in CO2) = 799 kJ/mol BE(C-H) = 414 kJ/mol BE(O-H) = 460 kJ/mol BE(O=O) = 498.7 kJ/mol


A) 1180 kJ
B) 447 kJ
C) 364 kJ
D) 1230 kJ
E) 16.8 kJ

F) B) and E)
G) C) and D)

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The Lewis dot symbol for the a lead atom is


A) The Lewis dot symbol for the a lead atom is A)    B)    C)    D)    E)
B) The Lewis dot symbol for the a lead atom is A)    B)    C)    D)    E)
C) The Lewis dot symbol for the a lead atom is A)    B)    C)    D)    E)
D) The Lewis dot symbol for the a lead atom is A)    B)    C)    D)    E)
E) The Lewis dot symbol for the a lead atom is A)    B)    C)    D)    E)

F) C) and D)
G) D) and E)

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The polarity of covalent bonds increases as the percent ionic character increases.

A) True
B) False

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Which of the bonds below would have the greatest polarity (i.e., highest percent ionic character) ?


A) Si - P
B) Si - S
C) Si - Se
D) Si - Cl
E) Si - I

F) C) and D)
G) B) and E)

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