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Maple syrup is mostly a solution of sucrose in water.Calculate the molality of the syrup if a sample freezes at -0.50°C, assuming the solute is pure sucrose. [For water, Kf is 1.86°C/m.]

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At 10 \circ C one volume of water dissolves 3.10 volumes of chlorine gas at 1.00 atm pressure.What is the Henry's Law constant in mol/L·atm?


A) 3.8
B) 0.043
C) 36.
D) 3.1
E) 0.13

F) A) and C)
G) A) and D)

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The solubility of CO2 gas in water


A) increases with increasing temperature.
B) decreases with decreasing temperature.
C) decreases with increasing temperature.
D) is not dependent on temperature.

E) C) and D)
F) B) and C)

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Which of the following compounds should be soluble in CCl4?


A) NaCl
B) H2O
C) NaOH
D) C8H18
E) None of these

F) A) and B)
G) D) and E)

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Automobile radiators usually carry a sticker that indicates that they must contain an antifreeze solution for proper operation, winter or summer.Why should you not use ordinary water during the summer?

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The antifreeze will lower the vapor pres...

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The vapor pressure of water at 20°C is 17.5 mmHg. What is the vapor pressure of water over a solution prepared from 2.00 * 102 g of sucrose (C12H22O11) and 3.50 * 102 g water?


A) 0.51 mmHg
B) 16.0 mmHg
C) 17.0 mmHg
D) 18.0 mmHg
E) 19.4 mmHg

F) A) and B)
G) C) and D)

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Consider a 0.90 M Al(NO3) 3 solution. This solution has a nitrate ion concentration of


A) 0.30 M
B) 0.90 M
C) 0.0 M
D) 8.1 M
E) 2.7 M

F) A) and E)
G) C) and D)

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Explain the following, on the basis of osmosis or osmotic pressure: Drinking salt water actually dehydrates our tissues.

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The water passes fro...

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A solution that contains 55.0 g of ascorbic acid (VitaminC) in 250.g of water freezes at -2.34°C. Calculate the molar mass (in units of g/mol) of the solute. Kf of water is 1.86°C/m.


A) 1.26
B) 10.9
C) 43.6
D) 175
E) 277

F) A) and E)
G) A) and C)

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Thyroxine, an important hormone that controls the rate of metabolism in the body, can be isolated from the thyroid gland. If 0.455 g of thyroxine is dissolved in 10.0 g of benzene, the freezing point of the solution is 5.144°C.Pure benzene freezes at 5.444°C and has a Kf of 5.12°C/m.What is the molar mass of thyroxine?

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What is the approximate Na+ ion concentration in a 0.75 M Na2CO3 solution?


A) 0.375 M
B) 0.75 M
C) 1.25 M
D) 1.50 M
E) 2.25 M

F) D) and E)
G) B) and C)

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What is the molar mass of toluene if 0.85 g of toluene depresses the freezing point of 100.g of benzene by 0.47°C? Kf of benzene is 5.12°C/m.


A) 92.6 g/mol
B) 78.0 g/mol
C) 10.7 g/mol
D) 81.8 g/mol
E) 927 g/mol

F) D) and E)
G) A) and B)

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When 24.0 g of glucose (a nonelectrolyte) are dissolved in 500.g of water, the solution has a freezing point of -0.47°C. What is the molar mass of glucose? Kf of water is 1.86°C/m.


A) 41.9 g
B) 47.5 g
C) 54.9 g
D) 178 g
E) 190.g

F) A) and B)
G) A) and C)

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What is the molarity and molality of a solution that is 10.00 % by mass potassium hydrogen carbonate (KHCO3, 100.11 g/mol)and has a density of 1.0650 g/mL?

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Some KCl is dissolved in water 25°C, where it completely dissociates.The vapor pressure of pure water at 25°C is 28.3 mmHg. Estimate the mass in grams of KCl needed per liter of pure water to reduce the vapor pressure of water at 25°C by 5%.

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How many liters of ethylene glycol antifreeze (C2H6O2)would you add to your car radiator containing 15.0 L of water if you needed to protect your engine to -17.8°C? (The density of ethylene glycol is 1.1 g/mL. For water, Kf = 1.86°C/m.)

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Explain the following, on the basis of osmosis or osmotic pressure: When sprinkled with sugar, a dish of sliced fruit will form its own juice.

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The water inside the fruit cel...

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The term "proof" is defined as twice the percent by volume of pure ethanol in solution.A solution that is 95% ethanol is 190 proof.What is the molarity of ethanol in a 92-proof ethanol/water solution? (Given: density of ethanol = 0.80 g/cm3; density of water = 1.0 g/cm3)

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Heat of solution


A) is never positive ( Δ\Deltasoln \le 0) , because the solute-solvent attraction is never weaker than the combination of the solute-solute attraction and solvent-solvent attraction.
B) is always positive ( Δ\Deltasoln > 0) , because the solute-solvent attraction is always weaker than the combination of the solute-solute attraction and solvent-solvent attraction.
C) is always zero ( Δ\Deltasoln = 0) , because the solute-solvent attraction is defined as the average of the solute-solute attraction and solvent-solvent attraction.
D) is always negative ( Δ\Deltasoln < 0) , because the solute-solvent attraction is always stronger than the combination of the solute-solute attraction and solvent-solvent attraction.
E) may be positive, zero, or negative, depending on the relative strength of the solute-solvent, solute-solute, and solvent-solvent attractive forces.

F) All of the above
G) A) and D)

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What mass of ethanol, C2H5OH a nonelectrolyte, must be added to 10.0 L of water to give a solution that freezes at -10.0°C? Assume the density of water is 1.0 g/mL. Kf of water is 1.86°C/m.


A) 85.7 kg
B) 24.8 kg
C) 5.38 kg
D) 2.48 kg
E) 1.17 kg

F) None of the above
G) A) and B)

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